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Ammonium perchlorate (AP) and ammonium nitrate (AN) are the most commonly used oxidizers applied in solid propellants [1,2,3].In addition to their use in propellants, AP and AN are also employed as oxygen-enriched ingredients in explosives and pyrotechnics [4,5,6].Researchers have found that the performance of AP and AN is a function of their particle sizes.

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As the particle decreases in size, a greater proportion of atoms are found at the surface compared to those inside. For example, a particle of size 30 nm has 5% of its atoms on its surface, at 10 nm 20% of its atoms and at 3 nm 50% of its atoms. Thus nanoparticles have much greater surface area per unit mass compared with larger particles.

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